Production of Nanocarbon from Local Raw Materials

Abstract

This research aims at extraction of nanocarbon from local raw materials through a detailed study of its characteristics. The research involves study of thermal properties of fruit kernels (apricots) and walnut kernels, determining the optimal modes of the carbonization process for each type of raw material, developing a method for the synthesis of spherical granules by liquid granulation and determining the optimum concentration of the sulfuric acid solution used in granulation. Analysis of the results on the dynamic sorption of petroleum products showed that maximum sorption is achieved when using a sorbent obtained at 400∘C for 30 minutes. Temperature regimes have been optimized for obtaining sorbent from walnut shells with different carbon content. The hydrophobicity and oleophilic of their surface are common to all these materials. The dynamic conditions of the adsorption capacity processes under the sorbents were studied. Sorption efficiency and the specific capacity of sorbents were determined. It has been shown that the technological cycle of the studied sorbents can be repeated by repeated purification. When activated charcoal is used to purify water from petroleum products, the process of leaching with colloidal and finely dispersed mixtures – it was found that deaeration is necessary. The individual composition of the ether fraction OV-1 has a fixed liquid phase, Connected to Finuigan 4023 Automated GC/MS System mass spectrometer, It was determined by chromato-mass spectrometry in a capillary column 40 m long and 0.25 mm in internal diameter. The results of the Fure-IR spectroscopy study of samples based on the apricot peel, walnut peel, and walnut peel showed that winning symmetrical bands (2920 and 2851 cm−1) were observed in them, these bands belong to the C-H-valence oscillation belonging to the methyl and methylene groups. In the spectrum taken from a sample of apricot peel, absorption bands belonging to cellulose (1377 cm−1 and 1069 cm−1 ) were observed.

Thermogravimetric studies were performed on an STA 449C Jupiter synchronous thermal analysis instrument in the inert environment at a heating rate of 10∘ C/min in the temperature range of 25–1000∘C. Analysis of the porous structure parameters of carbon sorbents were carried out using the high-speed analyzer of gas sorption NOVA-1200e by the method of imaging nitrogen adsorption isotherms at a temperature of 77K.